Which of the following substances are present on the rubbing surface of a…
2023
Which of the following substances are present on the rubbing surface of a matchbox?
- A.
Glass powder and red phosphorus
- B.
White phosphorus and glass powder
- C.
Red phosphorus and magnesium
- D.
Potassium and white phosphorus
Show answer & explanation
Correct answer: A
Safety matches ignite through friction: the match head carries an oxidiser and fuel, while the separate striking surface on the box carries an abrasive plus a mild source of phosphorus. Because elemental white phosphorus is dangerously reactive, toxic, and ignites spontaneously in air, safety-match manufacture uses only its stable allotrope, red phosphorus, paired with a coarse abrasive that generates the localized heat needed to trigger ignition.
On a standard matchbox, that abrasive is powdered glass mixed with red phosphorus, coated onto the striking strip. When the match head is drawn across this rough, phosphorus-laced surface, friction generates enough heat to convert a trace of red phosphorus to white phosphorus vapour, which ignites and, in turn, sets off the oxidiser in the match head. This matches the composition glass powder and red phosphorus.
White phosphorus is pyrophoric and highly toxic (historically linked to 'phossy jaw' among matchworkers), so it is excluded from the striking mixture; only its safe red allotrope is used.
Magnesium is a flammable metal burned for its brilliant white light in flares and fireworks; it plays no role in generating striking friction and is absent from match compositions.
Elemental potassium reacts violently with atmospheric moisture and cannot be coated onto a consumer product; combined with unstable white phosphorus, this pairing is doubly unsafe and unused.
Hence, the substances present on the rubbing surface are glass powder and red phosphorus.