A vessel contains 2 litres (2000 mL) of pure acid. 200 mL of the mixture is…

2019

A vessel contains 2 litres (2000 mL) of pure acid. 200 mL of the mixture is taken out and replaced with 200 mL of water; this removal-and-replacement is carried out two more times, so it is done a total of 3 times in all. What is the amount of pure acid left in the vessel?

  1. A.

    1446 mL

  2. B.

    1400 mL

  3. C.

    1458 mL

  4. D.

    1428 mL

Attempted by 69 students.

Show answer & explanation

Correct answer: C

When a solution of volume V is repeatedly diluted by removing a fixed volume v and replacing it with the same volume of a different liquid, the fraction of the original substance retained after one such step is (1 − v/V). Repeating the process n times leaves V × (1 − v/V)n of the substance, because each step removes a FRACTION of whatever is currently present rather than a fixed amount — so the quantity shrinks geometrically, not linearly.

  1. Convert the volume to millilitres: V = 2 litres = 2000 mL.

  2. Each replacement removes v = 200 mL from the vessel, so the fraction of acid retained per step = 1 − 200/2000 = 0.9.

  3. The removal-and-replacement is carried out a total of n = 3 times (the first time, plus two more).

  4. Apply the formula: remaining acid = 2000 × (0.9)3 = 2000 × 0.729 = 1458 mL.

Cross-check by tracking each step individually: after the 1st replacement, acid = 2000 × 0.9 = 1800 mL; after the 2nd, acid = 1800 × 0.9 = 1620 mL; after the 3rd, acid = 1620 × 0.9 = 1458 mL — the same total as the formula gives.

So 1458 mL of pure acid remains in the vessel.

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